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Abstract. Air trapped in polar ice provides unique records of the pastatmospheric composition ranging from key greenhouse gases such as methane(CH4) to short-lived trace gases like ethane (C2H6) andpropane (C3H8). Recently, the comparison of CH4 recordsobtained using different extraction methods revealed disagreements in theCH4 concentration for the last glacial in Greenland ice. Elevatedmethane levels were detected in dust-rich ice core sections measureddiscretely, pointing to a process sensitive to the melt extraction technique. To shed light on the underlying mechanism, we performed targeted experiments and analyzed samples for methane and the short-chain alkanes ethane and propane covering the time interval from 12 to 42 kyr. Here, we report our findings of these elevated alkane concentrations, which scale linearly with the amount of mineral dust within the ice samples. The alkane production happens during the melt extraction step of the classic wet-extraction technique and reaches 14 to 91 ppb of CH4 excess in dusty ice samples. We document for the first time a co-production of excess methane, ethane, and propane, with the observed concentrations for ethane and propane exceeding their past atmospheric background at least by a factor of 10. Independent of the produced amounts, excess alkanes were produced in a fixed molar ratio of approximately 14:2:1, indicating a shared origin. The measured carbon isotopic signature of excess methane is (-47.0±2.9) ‰ and its deuterium isotopic signature is (-326±57) ‰. With the co-production ratios of excess alkanesand the isotopic composition of excess methane we established a fingerprintthat allows us to constrain potential formation processes. This fingerprintis not in line with a microbial origin. Moreover, an adsorption–desorptionprocess of thermogenic gas on dust particles transported to Greenlanddoes not appear very likely. Instead, the alkane pattern appears to beindicative of abiotic decomposition of organic matter as found in soils andplant leaves. 

Abstract. In 2013 an ice core was recovered from Roosevelt Island, an ice dome between two submarine troughs carved by paleo-ice-streams in the Ross Sea, Antarctica. The ice core is part of the Roosevelt Island Climate Evolution (RICE) project and provides new information about the past configuration of the West Antarctic Ice Sheet (WAIS) and its retreat during the last deglaciation. In this work we present the RICE17 chronology, which establishes the depth–age relationship for the top 754 m of the 763 m core. RICE17 is a composite chronology combining annual layer interpretations for 0–343 m (Winstrup et al., 2019) with new estimates for gas and ice ages based on synchronization of CH4 and δ18Oatm records to corresponding records from the WAIS Divide ice core and by modeling of the gas age–ice age difference. Novel aspects of this work include the following: (1) an automated algorithm for multiproxy stratigraphic synchronization of high-resolution gas records; (2) synchronization using centennial-scale variations in methane for pre-anthropogenic time periods (60–720 m, 1971 CE to 30 ka), a strategy applicable for future ice cores; and (3) the observation of a continuous climate record back to ∼65 ka providing evidence that the Roosevelt Island Ice Dome was a constant feature throughout the last glacial period. 

Wildfires emit mixtures of light‐absorbing aerosols (including black and brown carbon, BC and BrC, respectively) and more purely scattering organic aerosol (OA). BC, BrC, and OA interactions are complex and dynamic and evolve with aging in the atmosphere resulting in large uncertainties in their radiative forcing. We report microphysical, optical, and chemical measurements of multiple plumes from the Woodbury Fire (AZ, USA) observed at Los Alamos, NM, after 11–18 hr of atmospheric transit. This includes periods where the plumes exhibited little entrainment as well as periods that had become more dilute after mixing with background aerosol. Aerosol mass absorption cross sections (MAC) were enhanced by a factor of 1.5–2.2 greater than bare BC at 870 nm, suggesting lensing by nonabsorbing coatings following a core‐shell morphology. Larger MAC enhancement factors of 1.9–5.1 at 450 nm are greater than core‐shell morphology can explain and are attributed to BrC. MAC of OA (MAC_Org) at 450 nm was largest in intact portions of the plumes (peak value bounded between 0.6 and 0.9 m²/g [Org]) and decreased with plume dilution. We report a strong correlation between MAC_Org(450 nm) with the f_C2H4O2(a tracer for levoglucosan‐like species) of coatings and of bulk OA indicating that BrC in the Woodbury Fire was coemitted with levoglucosan, a primary aerosol. f_C2H4O2and MAC_Org(450 nm) are shown to vary between the edge and the core of plumes, demonstrating enhanced oxidation of OA and BrC bleaching near plume edges. Our process‐level finding can inform parameterizations of mixed BC, BrC, and OA properties for wildfire plumes in climate models.

 

Abstract. We present a 2700-year annually resolved chronology and snow accumulationhistory for the Roosevelt Island Climate Evolution (RICE) ice core, Ross IceShelf, West Antarctica. The core adds information on past accumulationchanges in an otherwise poorly constrained sector of Antarctica. The timescale was constructed by identifying annual cycles inhigh-resolution impurity records, and it constitutes the top part of theRoosevelt Island Ice Core Chronology 2017 (RICE17). Validation by volcanicand methane matching to the WD2014 chronology from the WAIS Divide ice coreshows that the two timescales are in excellent agreement. In a companionpaper, gas matching to WAIS Divide is used to extend the timescale for thedeeper part of the core in which annual layers cannot be identified. Based on the annually resolved timescale, we produced a record of past snowaccumulation at Roosevelt Island. The accumulation history shows thatRoosevelt Island experienced slightly increasing accumulation rates between700 BCE and 1300 CE, with an average accumulation of 0.25±0.02 mwater equivalent (w.e.) per year. Since 1300 CE, trends in the accumulationrate have been consistently negative, with an acceleration in the rate ofdecline after the mid-17th century. The current accumulation rate atRoosevelt Island is 0.210±0.002 m w.e. yr−1 (average since 1965 CE, ±2σ), and it is rapidly declining with a trend corresponding to0.8 mm yr−2. The decline observed since the mid-1960s is 8 times fasterthan the long-term decreasing trend taking place over the previouscenturies, with decadal mean accumulation rates consistently being belowaverage. Previous research has shown a strong link between Roosevelt Islandaccumulation rates and the location and intensity of the Amundsen Sea Low,which has a significant impact on regional sea-ice extent. The decrease inaccumulation rates at Roosevelt Island may therefore be explained in termsof a recent strengthening of the ASL and the expansion of sea ice in the easternRoss Sea. The start of the rapid decrease in RICE accumulation ratesobserved in 1965 CE may thus mark the onset of significant increases inregional sea-ice extent. 

High-resolution, well-dated climate archives provide an opportunity to investigate the dynamic interactions of climate patterns relevant for future projections. Here, we present data from a new, annually dated ice core record from the eastern Ross Sea, named the Roosevelt Island Climate Evolution (RICE) ice core. Comparison of this record with climate reanalysis data for the 1979–2012 interval shows that RICE reliably captures temperature and snow precipitation variability in the region. Trends over the past 2700 years in RICE are shown to be distinct from those in West Antarctica and the western Ross Sea captured by other ice cores. For most of this interval, the eastern Ross Sea was warming (or showing isotopic enrichment for other reasons), with increased snow accumulation and perhaps decreased sea ice concentration. However, West Antarctica cooled and the western Ross Sea showed no significant isotope temperature trend. This pattern here is referred to as the Ross Sea Dipole. Notably, during the Little Ice Age, West Antarctica and the western Ross Sea experienced colder than average temperatures, while the eastern Ross Sea underwent a period of warming or increased isotopic enrichment. From the 17th century onwards, this dipole relationship changed. All three regions show current warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea but increasing in the western Ross Sea. We interpret this pattern as reflecting an increase in sea ice in the eastern Ross Sea with perhaps the establishment of a modern Roosevelt Island polynya as a local moisture source for RICE.